Did you try these steps? Fill the iron with distilled or bottled water, if you can.
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To iron a shirt cuff, first unbutton it (to include the gauntlet button) and lay it out flat. First iron the inside of the cuff, and next the outside, moving all wrinkles from uneven fabric to the edges. Carefully iron around the buttons, and even on the backside. Ironing shirts is quicker and easier than you might think. Like T.M. Lewin says in the video above, it should only take an average of three minutes to properly iron a shirt, and that's doing it the right way. For cotton shirts, iron your shirt slightly damp on the side you’re ironing, with a hot iron. Iron lengthwise, not in circular motions, to avoid damaging the material. For thicker fabrics (such as an Oxford shirt), ironing both sides of the fabric will produce the best results.